Catalytic enantioselective addition of diethylzinc to aldehydes using aziridine based chiral ligands
Tetrahedron Asymmetry, cilt.18, sa.8, ss.1013-1016, 2007 (SCI-Expanded, Scopus)
- Yayın Türü: Makale / Tam Makale
- Cilt numarası: 18 Sayı: 8
- Basım Tarihi: 2007
- Doi Numarası: 10.1016/j.tetasy.2007.04.013
- Dergi Adı: Tetrahedron Asymmetry
- Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
- Sayfa Sayıları: ss.1013-1016
- Lokman Hekim Üniversitesi Adresli: Hayır
Özet
The readily available ferrocenyl substituted aziridinylmethanol 1 (FAM-1) was used as a chiral catalyst in the diethylzinc addition reaction to aromatic and aliphatic aldehydes to give secondary alcohols in high yields and up to 99% enantiomeric excess at room temperature. The catalyst can be recovered and used without losing its activity. © 2007 Elsevier Ltd. All rights reserved.