Synthesis and Crystal Structure Determination of a Dimeric Complex of Dimethylammoniumbis(p-tert-butylcatecholato) borate

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TOMBUL M., BIYIKOĞLU M., BULUT A., GÜVEN K., IşILAR Ö.

X-ray Structure Analysis Online, vol.36, no.1, pp.27-29, 2020 (ESCI) identifier

  • Publication Type: Article / Article
  • Volume: 36 Issue: 1
  • Publication Date: 2020
  • Doi Number: 10.2116/xraystruct.36.27
  • Journal Name: X-ray Structure Analysis Online
  • Journal Indexes: Emerging Sources Citation Index (ESCI), Scopus
  • Page Numbers: pp.27-29
  • Lokman Hekim University Affiliated: Yes

Abstract

© 2020 UKSS and NASSThe structure of a dimeric complex, namely dimethylammoniumbis{(p-tert-butylcatecholato) borate}, was determined by X-ray crystallography. The compound crystallized in a triclinic system, and was characterized to be in the space group P-1, with cell parameters a = 11.929(7)Å, b = 16.833(6)Å, c = 11.259(11)Å, α = 93.75(5)°, β = 91.00(7)°, γ = 100.37(4)°, Z = 4, and V = 2218(3)Å3. The crystal packing is conducted by intermolecular/intramolecular N–H···O hydrogen bonds. The B atom adopts a distorted tetrahedral geometry with four O atoms of p-tert-butylcatechol ligands.