Alkyl lewis acid catalyzed syntheses of dicarbonyl ferrocenes

Tombul M., Gemici S., BULUT A.

Asian Journal of Chemistry, cilt.22, sa.9, ss.7070-7074, 2010 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 22 Sayı: 9
  • Basım Tarihi: 2010
  • Dergi Adı: Asian Journal of Chemistry
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.7070-7074
  • Anahtar Kelimeler: Diferrocenoyl ketones, Ferrocenoyls, Ferrocene derivatives, Alkyl Lewis acid, Bronsted base, Acylation, SELF-ASSEMBLED MONOLAYERS, ENE REACTIONS, ALDEHYDES, CHLORIDE, COMPLEXES
  • Lokman Hekim Üniversitesi Adresli: Hayır

Özet

A series of diferrocenoyl compounds; succinyl (1), glutaryl (2), adipoyl (3), suberoyl (4) and sebacoyl ferrocene (5) were synthesized from the reaction of ferrocene with EtAlCl2. Compared to the conventional methods reported in the literature, the yields obtained from these reactions are found to be higher than the typical catalyst.